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Nano-sized inorganic compounds have attracted a great deal of scientific and technical interests owing to their unique physical and chemical properties, which bulk materials may not possess. Because nanoparticles have a large surface area to volume ratio, the
state of the surface molecules plays a key role in determining their properties.
Recently, a surface modification of
nanoparticles with a functional monolayer or a polymer shell has been reported to provide tailored surface properties of nanoparticles. In contrast, a nanoparticle coating on oxides or other inorganic compounds has remained a technical challenge, and has not been reported in the literature.
Recently, we discovered that AlPO4 nanoparticle-coated LiCoO2 showed a remarkable enhancement of the electrochemical and thermal properties, compared to bare LiCoO2 and LiCoO2 coated with other metal oxides.
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The
mesopores play an important role in reducing possible
aggregationof Sn particles, and act a "buffer
zone" which accommodates the volume change
of the Sn phase during Li alloying/dealliying.
Our
approach for enhancing the structural stability
of tin phosphate is to incorporate mesoporous structures
as a buffer layer to alleviate the volume expansion
of the tin phosphate anode during lithiation/delithiation.
We
believe that this novel mesoporous tin phosphate/Sn2P2O7
composite has an enormous potential for use in Li-battery
anode material.
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매일신문,
영남일보,
전자신문>



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